| 1 | Queen Elizabeth's School, Barnet | Barnet | 87.3% | 605(2015/16–2019/20) |
| 2 | The Henrietta Barnett School | Barnet | 85.8% | 515(2015/16–2019/20) |
| 3 | Brampton Manor Academy | Newham | 80.5% | 1,003(2015/16–2019/20) |
| 4 | The Tiffin Girls' School | Kingston upon Thames | 79.2% | 611(2015/16–2019/20) |
| 5 | King's College London Maths School | Lambeth | 78.9% | 278(2015/16–2019/20) |
| 6 | St Olave's and St Saviour's Grammar School | Bromley | 77.3% | 883(2015/16–2019/20) |
| 7 | Wilson's School | Sutton | 76.7% | 593(2015/16–2019/20) |
| 8 | Altrincham Grammar School for Girls | Trafford | 76.7% | 680(2015/16–2019/20) |
| 9 | Reading School | Reading | 74.7% | 625(2015/16–2019/20) |
| 10 | London Academy of Excellence | Newham | 74.5% | 857(2015/16–2019/20) |
| 11 | King Edward VI Grammar School, Chelmsford | Essex | 74.0% | 743(2015/16–2019/20) |
| 12 | Pate's Grammar School | Gloucestershire | 73.8% | 824(2015/16–2019/20) |
| 13 | King Edward VI Camp Hill School for Boys | Birmingham | 73.0% | 539(2015/16–2019/20) |
| 14 | The Blue Coat School | Liverpool | 71.8% | 668(2015/16–2019/20) |
| 15 | The Latymer School | Enfield | 71.3% | 878(2015/16–2019/20) |
| 16 | Tiffin School | Kingston upon Thames | 71.0% | 772(2015/16–2019/20) |
| 17 | The Judd School | Kent | 70.5% | 707(2015/16–2019/20) |
| 18 | Newham Collegiate Sixth Form Centre, City of London Academy | Newham | 69.6% | 569(2018/19–2019/20) |
| 19 | King Edward VI Camp Hill School for Girls | Birmingham | 69.1% | 635(2015/16–2019/20) |
| 20 | Altrincham Grammar School for Boys | Trafford | 69.1% | 697(2015/16–2019/20) |
| 21 | Kendrick School | Reading | 69.0% | 505(2015/16–2019/20) |
| 22 | Colchester Royal Grammar School | Essex | 68.8% | 691(2015/16–2019/20) |
| 23 | St Michael's Catholic Grammar School | Barnet | 68.5% | 463(2015/16–2019/20) |
| 24 | King Edward VI School | Warwickshire | 68.4% | 587(2015/16–2019/20) |
| 25 | Dartford Grammar School | Kent | 67.5% | 1,159(2015/16–2019/20) |
| 26 | Loreto Grammar School | Trafford | 66.8% | 497(2015/16–2019/20) |
| 27 | Sutton Grammar School | Sutton | 66.7% | 549(2015/16–2019/20) |
| 28 | Dr Challoner's Grammar School | Buckinghamshire | 66.5% | 842(2015/16–2019/20) |
| 29 | Dame Alice Owen's School | Hertfordshire | 66.0% | 829(2015/16–2019/20) |
| 30 | King Edward VI Five Ways School | Birmingham | 65.1% | 789(2015/16–2019/20) |
| 31 | Dr Challoner's High School | Buckinghamshire | 65.0% | 633(2015/16–2019/20) |
| 32 | Colyton Grammar School | Devon | 64.8% | 439(2015/16–2019/20) |
| 33 | Tonbridge Grammar School | Kent | 63.8% | 562(2015/16–2019/20) |
| 34 | Exeter Mathematics School | Devon | 63.6% | 213(2015/16–2019/20) |
| 35 | The London Oratory School | Hammersmith and Fulham | 63.5% | 673(2015/16–2019/20) |
| 36 | The Cardinal Vaughan Memorial RC School | Kensington and Chelsea | 62.6% | 696(2015/16–2019/20) |
| 37 | The Skinners' School | Kent | 62.6% | 524(2015/16–2019/20) |
| 38 | Bishop Vesey's Grammar School | Birmingham | 62.4% | 740(2015/16–2019/20) |
| 39 | Nonsuch High School for Girls | Sutton | 62.2% | 683(2015/16–2019/20) |
| 40 | Harris Westminster Sixth Form | Westminster | 61.6% | 894(2015/16–2019/20) |
| 41 | Hockerill Anglo-European College | Hertfordshire | 61.6% | 332(2015/16–2019/20) |
| 42 | The Camden School for Girls | Camden | 61.0% | 877(2015/16–2019/20) |
| 43 | London Academy of Excellence Tottenham | Haringey | 60.8% | 256(2018/19–2019/20) |
| 44 | Sir William Borlase's Grammar School | Buckinghamshire | 60.7% | 819(2015/16–2019/20) |
| 45 | Chelmsford County High School for Girls | Essex | 60.4% | 471(2015/16–2019/20) |
| 46 | Ripon Grammar School | North Yorkshire | 60.4% | 565(2015/16–2019/20) |
| 47 | Wallington County Grammar School | Sutton | 58.7% | 684(2015/16–2019/20) |
| 48 | Watford Grammar School for Boys | Hertfordshire | 58.4% | 754(2015/16–2019/20) |
| 49 | Westcliff High School for Boys Academy | Southend-on-Sea | 58.2% | 645(2015/16–2019/20) |
| 50 | Durham Johnston Comprehensive School | County Durham | 58.1% | 649(2015/16–2019/20) |
| 51 | JFS | Brent | 58.0% | 960(2015/16–2019/20) |
| 52 | Watford Grammar School for Girls | Hertfordshire | 57.7% | 741(2015/16–2019/20) |
| 53 | Holland Park School | Kensington and Chelsea | 57.6% | 358(2015/16–2019/20) |
| 54 | Colchester County High School for Girls | Essex | 57.5% | 403(2015/16–2019/20) |
| 55 | Newstead Wood School | Bromley | 56.7% | 526(2015/16–2019/20) |
| 56 | Yavneh College | Hertfordshire | 55.7% | 374(2015/16–2019/20) |
| 57 | Tunbridge Wells Girls' Grammar School | Kent | 55.6% | 571(2015/16–2019/20) |
| 58 | Saint Ambrose College | Trafford | 55.3% | 403(2015/16–2019/20) |
| 59 | St Paul's Way Trust School | Tower Hamlets | 55.1% | 282(2015/16–2019/20) |
| 60 | Haberdashers' Adams | Telford and Wrekin | 54.8% | 621(2015/16–2019/20) |
| 61 | Parmiter's School | Hertfordshire | 54.6% | 766(2015/16–2019/20) |
| 62 | Sale Grammar School | Trafford | 54.2% | 702(2015/16–2019/20) |
| 63 | Wallington High School for Girls | Sutton | 54.1% | 804(2015/16–2019/20) |
| 64 | Stratford Girls' Grammar School | Warwickshire | 53.9% | 396(2015/16–2019/20) |
| 65 | Beaconsfield High School | Buckinghamshire | 53.3% | 571(2015/16–2019/20) |
| 66 | Wolverhampton Girls' High School | Wolverhampton | 53.1% | 481(2015/16–2019/20) |
| 67 | Aylesbury Grammar School | Buckinghamshire | 52.6% | 749(2015/16–2019/20) |
| 68 | Woodford County High School | Redbridge | 52.5% | 618(2015/16–2019/20) |
| 69 | Fortismere School | Haringey | 52.5% | 839(2015/16–2019/20) |
| 70 | The Royal Grammar School, High Wycombe | Buckinghamshire | 52.3% | 722(2015/16–2019/20) |
| 71 | Royal Latin School | Buckinghamshire | 52.0% | 790(2015/16–2019/20) |
| 72 | Stroud High School | Gloucestershire | 51.4% | 521(2015/16–2019/20) |
| 73 | Queen Mary's Grammar School | Walsall | 51.3% | 698(2015/16–2019/20) |
| 74 | Hills Road Sixth Form College | Cambridgeshire | 51.2% | 4,544(2015/16–2019/20) |
| 75 | Lancaster Girls' Grammar School | Lancashire | 51.1% | 543(2015/16–2019/20) |
| 76 | Cheadle Hulme High School | Stockport | 50.9% | 451(2015/16–2019/20) |
| 77 | Sir Thomas Rich's School | Gloucestershire | 50.9% | 772(2015/16–2019/20) |
| 78 | JCoSS | Barnet | 50.8% | 420(2015/16–2019/20) |
| 79 | Aylesbury High School | Buckinghamshire | 50.7% | 751(2015/16–2019/20) |
| 80 | Ashcroft Technology Academy | Wandsworth | 50.7% | 426(2015/16–2019/20) |
| 81 | King Edward VI Handsworth School | Birmingham | 50.3% | 540(2015/16–2019/20) |
| 82 | Lancaster Royal Grammar School | Lancashire | 50.3% | 569(2015/16–2019/20) |
| 83 | Cranbrook School | Kent | 49.9% | 525(2015/16–2019/20) |
| 84 | Sutton Coldfield Grammar School for Girls | Birmingham | 49.6% | 460(2015/16–2019/20) |
| 85 | Bishop Wordsworth's Church of England Grammar School | Wiltshire | 49.2% | 543(2015/16–2019/20) |
| 86 | Torquay Boys' Grammar School | Torbay | 48.9% | 570(2015/16–2019/20) |
| 87 | Waldegrave School | Richmond upon Thames | 48.6% | 570(2015/16–2019/20) |
| 88 | Mossbourne Community Academy | Hackney | 48.5% | 520(2015/16–2019/20) |
| 89 | Wembley High Technology College | Brent | 48.5% | 546(2015/16–2019/20) |
| 90 | Chesham Grammar School | Buckinghamshire | 48.5% | 732(2015/16–2019/20) |
| 91 | Torquay Girls' Grammar School | Torbay | 48.5% | 423(2015/16–2019/20) |
| 92 | Twyford Church of England High School | Ealing | 48.4% | 1,003(2015/16–2019/20) |
| 93 | Wirral Grammar School for Girls | Wirral | 47.5% | 581(2015/16–2019/20) |
| 94 | Lady Margaret School | Hammersmith and Fulham | 47.3% | 324(2015/16–2019/20) |
| 95 | Bristol Cathedral Choir School | Bristol, City of | 47.2% | 570(2015/16–2019/20) |
| 96 | Tapton School | Sheffield | 47.1% | 786(2015/16–2019/20) |
| 97 | Silverdale School | Sheffield | 47.1% | 680(2015/16–2019/20) |
| 98 | Langley Grammar School | Slough | 46.9% | 612(2015/16–2019/20) |
| 99 | Caistor Grammar School | Lincolnshire | 46.8% | 346(2015/16–2019/20) |
| 100 | Woodhouse College | Barnet | 46.7% | 2,695(2015/16–2019/20) |