| 1 | King's College London Maths School | Lambeth | 91.9% | 215(2019/20–2021/22) |
| 2 | Queen Elizabeth's School, Barnet | Barnet | 91.2% | 481(2019/20–2021/22) |
| 3 | Brampton Manor Academy | Newham | 89.5% | 1,167(2019/20–2021/22) |
| 4 | Wilson's School | Sutton | 87.7% | 491(2019/20–2021/22) |
| 5 | St Olave's and St Saviour's Grammar School | Bromley | 86.0% | 663(2019/20–2021/22) |
| 6 | Reading School | Reading | 85.9% | 526(2019/20–2021/22) |
| 7 | The Henrietta Barnett School | Barnet | 85.4% | 403(2019/20–2021/22) |
| 8 | King Edward VI Grammar School, Chelmsford | Essex | 83.0% | 554(2019/20–2021/22) |
| 9 | The Tiffin Girls' School | Kingston upon Thames | 82.0% | 480(2019/20–2021/22) |
| 10 | Pate's Grammar School | Gloucestershire | 82.0% | 660(2019/20–2021/22) |
| 11 | Colchester Royal Grammar School | Essex | 81.8% | 350(2019/20–2021/22) |
| 12 | Tiffin School | Kingston upon Thames | 81.4% | 681(2019/20–2021/22) |
| 13 | Altrincham Grammar School for Girls | Trafford | 81.3% | 542(2019/20–2021/22) |
| 14 | St Michael's Catholic Grammar School | Barnet | 80.6% | 350(2019/20–2021/22) |
| 15 | Sutton Grammar School | Sutton | 79.9% | 476(2019/20–2021/22) |
| 16 | The Blue Coat School | Liverpool | 79.3% | 476(2019/20–2021/22) |
| 17 | Dartford Grammar School | Kent | 79.3% | 896(2019/20–2021/22) |
| 18 | Altrincham Grammar School for Boys | Trafford | 78.5% | 544(2019/20–2021/22) |
| 19 | London Academy of Excellence | Newham | 78.4% | 701(2019/20–2021/22) |
| 20 | The Latymer School | Enfield | 78.0% | 652(2019/20–2021/22) |
| 21 | King Edward VI Camp Hill School for Girls | Birmingham | 77.7% | 496(2019/20–2021/22) |
| 22 | The Judd School | Kent | 77.4% | 664(2019/20–2021/22) |
| 23 | Dr Challoner's Grammar School | Buckinghamshire | 77.0% | 650(2019/20–2021/22) |
| 24 | King Edward VI School | Warwickshire | 76.3% | 485(2019/20–2021/22) |
| 25 | Michaela Community School | Brent | 75.7% | 95(2020/21–2021/22) |
| 26 | King Edward VI Camp Hill School for Boys | Birmingham | 75.7% | 480(2019/20–2021/22) |
| 27 | Tonbridge Grammar School | Kent | 75.3% | 410(2019/20–2021/22) |
| 28 | Colyton Grammar School | Devon | 74.8% | 360(2019/20–2021/22) |
| 29 | The London Oratory School | Hammersmith and Fulham | 74.6% | 527(2019/20–2021/22) |
| 30 | Dame Alice Owen's School | Hertfordshire | 74.4% | 624(2019/20–2021/22) |
| 31 | King Edward VI Five Ways School | Birmingham | 74.3% | 593(2019/20–2021/22) |
| 32 | Kendrick School | Reading | 74.3% | 397(2019/20–2021/22) |
| 33 | Exeter Mathematics School | Devon | 73.7% | 185(2019/20–2021/22) |
| 34 | Bishop Vesey's Grammar School | Birmingham | 73.3% | 617(2019/20–2021/22) |
| 35 | Newham Collegiate Sixth Form Centre, City of London Academy | Newham | 72.2% | 891(2019/20–2021/22) |
| 36 | Dr Challoner's High School | Buckinghamshire | 71.9% | 483(2019/20–2021/22) |
| 37 | The Skinners' School | Kent | 71.7% | 466(2019/20–2021/22) |
| 38 | Colchester County High School for Girls | Essex | 70.9% | 362(2019/20–2021/22) |
| 39 | Hockerill Anglo-European College | Hertfordshire | 70.7% | 227(2019/20–2021/22) |
| 40 | Stratford Girls' Grammar School | Warwickshire | 70.6% | 284(2019/20–2021/22) |
| 41 | Wallington County Grammar School | Sutton | 70.5% | 521(2019/20–2021/22) |
| 42 | Harris Westminster Sixth Form | Westminster | 70.3% | 859(2019/20–2021/22) |
| 43 | Newstead Wood School | Bromley | 70.2% | 493(2019/20–2021/22) |
| 44 | Nonsuch High School for Girls | Sutton | 69.1% | 587(2019/20–2021/22) |
| 45 | The Royal Grammar School, High Wycombe | Buckinghamshire | 68.7% | 589(2019/20–2021/22) |
| 46 | Westcliff High School for Boys Academy | Southend-on-Sea | 68.7% | 532(2019/20–2021/22) |
| 47 | The Cardinal Vaughan Memorial RC School | Kensington and Chelsea | 68.4% | 531(2019/20–2021/22) |
| 48 | Loreto Grammar School | Trafford | 68.2% | 386(2019/20–2021/22) |
| 49 | Parmiter's School | Hertfordshire | 68.0% | 579(2019/20–2021/22) |
| 50 | The Camden School for Girls | Camden | 67.7% | 651(2019/20–2021/22) |
| 51 | Chelmsford County High School for Girls | Essex | 67.6% | 367(2019/20–2021/22) |
| 52 | Sir William Borlase's Grammar School | Buckinghamshire | 67.3% | 650(2019/20–2021/22) |
| 53 | Saint Ambrose College | Trafford | 67.2% | 299(2019/20–2021/22) |
| 54 | Wallington High School for Girls | Sutton | 66.0% | 687(2019/20–2021/22) |
| 55 | Durham Johnston Comprehensive School | County Durham | 65.5% | 526(2019/20–2021/22) |
| 56 | Sutton Coldfield Grammar School for Girls | Birmingham | 65.4% | 408(2019/20–2021/22) |
| 57 | Beaconsfield High School | Buckinghamshire | 65.1% | 456(2019/20–2021/22) |
| 58 | Tunbridge Wells Girls' Grammar School | Kent | 64.7% | 433(2019/20–2021/22) |
| 59 | Cheadle Hulme High School | Stockport | 64.6% | 416(2019/20–2021/22) |
| 60 | Bishop Wordsworth's Church of England Grammar School | Wiltshire | 64.5% | 411(2019/20–2021/22) |
| 61 | Sale Grammar School | Trafford | 63.6% | 510(2019/20–2021/22) |
| 62 | Ripon Grammar School | North Yorkshire | 62.6% | 438(2019/20–2021/22) |
| 63 | King Edward VI Handsworth School | Birmingham | 62.4% | 472(2019/20–2021/22) |
| 64 | Royal Latin School | Buckinghamshire | 62.3% | 623(2019/20–2021/22) |
| 65 | Twyford Church of England High School | Ealing | 62.3% | 785(2019/20–2021/22) |
| 66 | Watford Grammar School for Boys | Hertfordshire | 62.0% | 594(2019/20–2021/22) |
| 67 | St George's School | Hertfordshire | 61.8% | 595(2019/20–2021/22) |
| 68 | Langley Grammar School | Slough | 61.8% | 484(2019/20–2021/22) |
| 69 | London Academy of Excellence Tottenham | Haringey | 61.7% | 619(2019/20–2021/22) |
| 70 | Holland Park School | Kensington and Chelsea | 61.3% | 209(2019/20–2021/22) |
| 71 | Newport Girls' High School Academy | Telford and Wrekin | 61.2% | 242(2019/20–2021/22) |
| 72 | Aylesbury High School | Buckinghamshire | 60.3% | 567(2019/20–2021/22) |
| 73 | Queen Mary's Grammar School | Walsall | 60.3% | 627(2019/20–2021/22) |
| 74 | Wycombe High School | Buckinghamshire | 60.1% | 527(2019/20–2021/22) |
| 75 | Watford Grammar School for Girls | Hertfordshire | 60.0% | 587(2019/20–2021/22) |
| 76 | Sir Thomas Rich's School | Gloucestershire | 59.8% | 569(2019/20–2021/22) |
| 77 | Lady Margaret School | Hammersmith and Fulham | 59.7% | 247(2019/20–2021/22) |
| 78 | Lancaster Girls' Grammar School | Lancashire | 59.4% | 374(2019/20–2021/22) |
| 79 | Woodhouse College | Barnet | 59.4% | 2,101(2019/20–2021/22) |
| 80 | Haberdashers' Adams | Telford and Wrekin | 59.3% | 496(2019/20–2021/22) |
| 81 | Mossbourne Community Academy | Hackney | 59.0% | 487(2019/20–2021/22) |
| 82 | Holyport College | Windsor and Maidenhead | 59.0% | 226(2019/20–2021/22) |
| 83 | JFS | Brent | 58.9% | 742(2019/20–2021/22) |
| 84 | Aylesbury Grammar School | Buckinghamshire | 58.7% | 582(2019/20–2021/22) |
| 85 | Woodford County High School | Redbridge | 58.7% | 466(2019/20–2021/22) |
| 86 | Wolverhampton Girls' High School | Wolverhampton | 58.6% | 433(2019/20–2021/22) |
| 87 | The St Marylebone CofE School | Westminster | 58.5% | 488(2019/20–2021/22) |
| 88 | Chesham Grammar School | Buckinghamshire | 58.4% | 585(2019/20–2021/22) |
| 89 | Hills Road Sixth Form College | Cambridgeshire | 58.4% | 3,740(2019/20–2021/22) |
| 89 | Torquay Girls' Grammar School | Torbay | 58.4% | 306(2019/20–2021/22) |
| 91 | Yavneh College | Hertfordshire | 58.3% | 341(2019/20–2021/22) |
| 92 | Torquay Boys' Grammar School | Torbay | 58.2% | 404(2019/20–2021/22) |
| 93 | Waldegrave School | Richmond upon Thames | 58.0% | 564(2019/20–2021/22) |
| 94 | Ashcroft Technology Academy | Wandsworth | 57.6% | 333(2019/20–2021/22) |
| 95 | Lancaster Royal Grammar School | Lancashire | 57.4% | 489(2019/20–2021/22) |
| 96 | Lawrence Sheriff School | Warwickshire | 56.9% | 535(2019/20–2021/22) |
| 97 | JCoSS | Barnet | 56.7% | 438(2019/20–2021/22) |
| 98 | Southend High School for Boys | Southend-on-Sea | 56.5% | 592(2019/20–2021/22) |
| 99 | Ermysted's Grammar School | North Yorkshire | 56.3% | 325(2019/20–2021/22) |
| 100 | The Grey Coat Hospital | Westminster | 56.2% | 375(2019/20–2021/22) |